المنهاج--(Carbanion)

College of science
Dep.of Chemistry/organic chemistry/3rd year
2011-2012
Nadhir Najim Abdullah Jafar
1. Carboxylic acid
2. Carboxylic acid derivative
3. Stereochemistry
4. Amines
5. Phenols
6. Aryl halide
7. Carboniuon I
8. Carboniuon II
9. ?-?-unsaturated carbonyl compounds
10. Fused aromatic compounds
11. Heterocyclic compounds
12. Perecyclic reaction
جمهورية العراق
وزارة التعليم العالي والبحث العلمي
جامعة بابل
كليـــــة العلوم
قسم
الدراسات الأولية / الدراسات العليا



رقم المقرر الدولي العدد:



Course NO: التأريخ : / /



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1-اسم المقرر : .كيمياء عضوية......................... فصلي ............................. سنوي …..نعم.....
إجباري ...............(اجباري)............... اختياري .................................. رقم الإصدار...................تاريخ الإصدار................
2- عدد الوحدات : .....6................ عدد الساعات الإجمالي .....6...... النظري ..............3........ العملي ..........3...............
3- المرحلة الدراسية : الرابعة.

اسم التدريسي أو التدريسيين






الشهادة واللقب العلمي





التخصص الدقيق







5- لغة تدريس المقرر : عربي انكليزي أخرى






برنامج المقرر
1. Introduction:
It is an important branch of chemistry it role an essential method for increasing the knowledge of student in organic chemistry. This program is complete the fundamentals in the organic chemistry.
2. Aim of course:

1) Carboxylic Acid.
2) Naming, Structure and physical properties, Dissociation of carboxylic acid
3) Substituent effect on acidity.
4) Substituent effect in substituent Benzoic acids.
5) Preparation of carboxylic acids.
6) Reaction of carboxylic acids.
7) Reduction of carboxylic acids.
8) Carboxylic Acid derivative And Nucleophilic Acyl Substitutions Reactions.
9) Naming all derivative and Nitriles.
10) Nucleophilic acyl substitutions reactions.
11) Nucleophilic acyl substitutions reactions of carboxylic acids.
12) Chemistry of acid Halides.
13) Chemistry of acid Anhydrides.
14) Chemistry of Ester.
15) Chemistry of Amide.
16) Chemistry of Nitriles.
17) Stereochemistry
18) Enantiomers and the tetrahedral carbon.
19) Handedness in molecules.
20) Chirality.
21) Optical activity.
22) Specific rotation.
23) Specific rotation.
24) Sequence rule for specification of configuration.
25) Diastereomers.
26) Meso compounds.
27) Molecules with more than two Chirality centers.
28) Racemic mixtures.
29) Fisher projections, Assigning R,S configurations.
30) Stereochemistry of SN1,SN2 reactions.
31) Phenol
32) Naming, properties and hydrogen bonding, Acidity, Reactions, Preparation and use of phenol.
33) Carbonyl ?- Substitution Reactions.
34) Keto-Enol Tautomerism, Reactivity, mechanism, ?- Haloganation of aldehydes and ketones.
35) Hell-Volhard-Zelinskii reaction, Reactivity of enolate ions, Halogenation of enolate ions (Haloform reaction).
36) Carbonyl Condensation reactions, Mechanism of carbonyl condensation reactions, Aldol reaction.
37) Carbonyl condensation reactions versus ?- Substitution Reactions.Synthesis of Enones.
38) Mixed Aldol reactions, Claisen condensation reaction, The Dieckman cylcization
39) The Michael reaction, Stork enamine reaction, Robinson Annulation reaction.
40) Amines
41) Naming, structure and bonding, properties.
42) Basicity of amines and substituted aryl amine.
43) Synthesis of amines.
44) Reactions of amines and aryl amines.
45) The Hofman elimination, Electrophilic aromatic substitutions in aryl amines.
46) Synthetic transformations of aryl diazoium salts.
47) Heterocylic compounds, naming.
48) Five- membered unsaturated hetocyclic.
49) Structures of Pyrrole, Furan, and Thiophene, Electrophilic substitution reactions of pyrrole, furran and thiophene, Pyriden, a six membered ring.
50) Electrophilic and Nucleophilic substitution reactions of Pyridine.


3. Contain:
# of week Contain
1. Carboxylic Acid naming, Structure and physical properties, Dissociation of carboxylic acid.
2. Substituent effect on acidity, substituent effect in substituent Benzoic acids, preparation of carboxylic acids.
3. Reaction of carboxylic acids, reduction of carboxylic acids.
4. Carboxylic Acid derivative And Nucleophilic Acyl Substitutions Reactions, naming all derivative and Nitriles.
5. Nucleophilic acyl substitutions reactions, nucleophilic acyl substitutions reactions of carboxylic acids.
6. Chemistry of acid Halides, Chemistry of acid Anhydrides, chemistry of Ester, chemistry of mide, Chemistry of Nitriles.
7. Stereochemistry
8. Enantiomers and the tetrahedral carbon, Handedness in molecules; Chirality, optical activity, specific rotation.
9. Specific rotation, Sequence rule for specification of configuration.
10. Diastereomers, Meso compounds, Molecules with more than two Chirality centers, Racemic mixtures.
11. Fisher projections, Assigning R,S configurations. Stereochemistry of SN1,SN2 reactions.
12. Phenol
13. Naming, properties and hydrogen bonding, Acidity, Reactions, Preparation and use of phenol.
14. Carbonyl ?- Substitution Reactions. Keto-Enol Tautomerism, Reactivity, mechanism, ?- Haloganation of aldehydes and ketones.
15. Hell-Volhard-Zelinskii reaction, Reactivity of enolate ions, Halogenation of enolate ions (Haloform reaction).
16. Carbonyl Condensation reactions, Mechanism of carbonyl condensation reactions, Aldol reaction.
17. Carbonyl condensation reactions versus ?- Substitution Reactions.Synthesis of Enones.
18. Mixed Aldol reactions, Claisen condensation reaction, The Dieckman cylcization.
19. The Michael reaction, Stork enamine reaction, Robinson Annulation reaction.
20. Amines, naming, structure and bonding, properties
21. Basicity of amines and substituted aryl amine.
22. Synthesis of amines.
23. Reactions of amines and aryl amines.
24. The Hofman elimination, Electrophilic aromatic substitutions in aryl amines.
25. Synthetic transformations of aryl diazoium salts.
26. Heterocylic compounds, naming.
27. Five- membered unsaturated hetocyclic.
28. Structures of Pyrrole, Furan, and Thiophene.
29. Electrophilic substitution reactions of pyrrole, furran and thiophene, Pyriden, a six membered ring.
30. Electrophilic and Nucleophilic substitution reactions of Pyridine.



رابعا": تذكر طرائق التدريس المعتمدة لتنفيذ المقرر:
1. يتم التعليم من خلال المناقشة وطرح الاسئلة بين الطالب والتدريسي.
2. يطالب كل طالب من اجراء محاورة علمية تناقش في الصف ويعطى الطالب الوقت الكافي لاداء ذلك.
3. استخدام اسلوب المحاضرة.

خامسا": توزع درجات المقرر وفقا لواحد أو أكثر مما يأتي:

درجة السعي النظري 25%
درجة السعي العملي 25%
درجة الامتحان النهائي 50 %



سادسا" المصادر والمراجع :
1. Organic Chemistry : By Morrison and Boyed 3rd edition 1974.
2. Organic Chemistry : By John McMurey 7th edition 2009.
3. Organic Chemistry : By Francis A. Carey 4th edition 2000










المدرس الدكتور
ناظر نجم عبدالله قاسم حسن كاظم
اسم التدريسي ر. القسم